Product ID:SUPEROX 709, 46-709
MSDS Date:01/16/1992
FSC:6850
NIIN:00N003339
MSDS Number: CCBQV

REICHHOLD CHEMICALS INC

RESEARCH TRIANGLE PARK
DURHAM, NC 27709
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 800-874-1807

Cage: 6D992

REICHHOLD CHEMICAL INC

RESEARCH TRIANGLE PARK, NC 27709 US

Telephone: 800-874-5403

Cage: 6D992

TO OUTDOORS FOR DISP. WASH AREA W/DETERGENT &

RTECS: 9999999ZZ

OF THE BAG/CNTNR THORO W/WATER & SEAL. THIS MATL

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QTYS EQUAL TO OR GREATER THAN RQ ARE SUBJECT TO

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METHYL ETHYL KETONE PEROXIDE RQ = 10 LBS. DIMETHYL

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METHYL ETHYL KETONE RQ = 5000 LBS.

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PACKAGING & RECORDKEEPING STDS. FOR

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EPA'S RCRA HOTLINE (800-424-9346 OR 202-382-3000).

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BELOW 80F IS RECOM FOR MAX SHELF-LIFE

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A RESIN SOLN, PROMPTLY & THORO MIX AFTER ADDN

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PRODUCT. READ & UNDERSTAND LABEL, SPI SAFETY WALL

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AND FULL LENGTH FACESHIELD .

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2-BUTANONE, PEROXIDE; (METHYL ETHYL KETONE PEROXIDE) (MEKP)

CAS: 1338-23-4

RTECS: EL9450000

Fraction By Weight: 40%

OSHA PEL 0.7 PPM, C

ACGIH TLV: 0.2 PPM, C

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

PHTHALIC ACID, DIMETHYL ESTER; (DIMETHYL PHTHALATE) (SARA

CAS: 131-11-3

RTECS: TI1575000

Fraction By Weight: 48%

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

HYDROGEN PEROXIDE (SARA 302)

CAS: 7722-84-1

RTECS: MX0900000

Fraction By Weight: 2.5%

OSHA PEL 1 PPM

ACGIH TLV: 1 PPM

2-BUTANONE; (METHYL ETHYL KETONE) (SARA 313) (CERCLA)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 4%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM; 300 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

IRRIT PERSISTS, CNTCT MD. DISCARD CONTAMD

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VICTIM TO WELL VENT AREA; THEN IF DFCLTY NOTED IN

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LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:METHYL ETHYL KETONE PEROXIDE IS HIGHLY
IRRITATING TO THE SKIN AND RESPIRATORY TRACT. EYE CONTACT MAY CAUSE
BLINDNESS. INHALATION OF FUMES OR VAPORS MAY RESULT IN HEADACHE,
DIZZINESS, SNEEZING, INCOORD INATION AND CNS DEPRESSION.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: RINSE EYES IMMED (SECONDS COUNT) W/WATER & CONTINUE
WASHING FOR AT LEAST 15 MIN. CALL MD AT ONCE. INGEST: DRINK LG AMTS
OF MILK OR WATER & OBTAIN IMMED MED ATTN FOR LAVAGE (STOMACH WASH).
DO NOT INDUCE VOMIT. SKIN: WASH AFFECTED AREAS IMMED W/SOAP &
WATER. REMOVE CONTAMD CLTHG & SHOES & AGAIN WASH THORO W/SOAP &
WATER. IF SKIN IS IRRITATED, APPLY AN OINTMENT SUCH AS LANOLIN. IF
(ING 5)

Flash Point Method:SCC
Flash Point:>140F,>60C
Extinguishing Media:WATER MOST EFFECTIVE. ALSO WATER FOG, CARBON
DIOXIDE AND FOAM. CAUTION! DRY CHEMICAL CAN CAUSE MEKP TO REIGNITE!
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
PERS EVACUATION PRIMARY. BLAZE FOUGHT FROM SAFE DIST OR FROM
EXPLO-PROTECTED LOCATION. NON-BURNING (SUPDAT)
Unusual Fire/Explosion Hazard:IF CONFINED IN A RIGID CNTNR (GLASS,
METAL, THICK PLASTIC, ETC) IT COULD RUPTURE VIOLENTLY. EXPOS TO
TEMP OF 145F OR GREATER MAY RSLT IN VIOLENT DECOMPOSITION.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT & COVER W/INERT
NON-COMBUST ABSORB MATL TO CNTN SPILLAGE. EXPANDED MICA OR CLEAN
MOIST SAND ARE SUITABLE ABSORBS. GATHER ABSORBED MASS W/NON-SPKG
TOOLS TO CLEAN POLYETHYLEN E OR POLYPROPYLENE BAG OR CNTNR & MOVE
(ING 7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE AWAY FROM OTHER MATL IN COOL
PLACE IN ORIGINAL CNTNRS & AWAY FROM ANY SOURCE OF DIRECT SUNLIGHT,
HEAT, FLAME OR SPKS. STOR IN COOL AREA (ING 14)
Other Precautions:DO NOT ADD TO HOT MATL & AVOID ALL SOURCES OF CONTAM.
ONLY GLASS, POLYPROPYLENE, TEFLON(R), POLYETHYLENE, CERAMIC CNTNRS,
FUNNELS OR MEASURING DEVICES SHOULD BE USED TO AVOID METAL CONTAM
DURING HNDLG . WHEN ADDING THIS MATL TO (ING 15)

Respiratory Protection:A NIOSH/MSHA APPROVED CANISTER-TYPE RESPIRATOR
MUST BE WORN TO PREVENT THE INHALATION OF VAPORS WHEN THE TLV OR
PEL IS EXCEEDED.
Ventilation:GEN VENT IS REQD DURING NORM USE. LOC VENT MAY BE REQD
DURING CERTAIN OPERATIONS TO KEEP EXPOS LEVELS BELOW LISTED LIMS.
Protective Gloves:CHEM RESISTANT PLASTIC OR RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 17)
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:DISCARD DETERIORATED GLOVES PROMPTLY.
Supplemental Safety and Health
FIRE FIGHT PROC: MATL SHOULD BE RELOCATED TO SAFE AREA AS SOON AS POSS.
WATER SPRAY SHOULD BE PLACED IN ALL CNTNRS EXPOS TO EXCESS HEAT.
HEAT OF DECOMP OF PEROXIDES ADDS TO HEAT OF FIRE. DRY CHEM FIRE
EXTING MAY CATALYZE DECOMPOSITION. MATL TO AVOID: PROMOTERS OR
PROMOTED RESINS.

Boiling Pt:B.P. Text:DECOMPOSES
Vapor Density:HVR/AIR
Spec Gravity:1.11-1.17
Evaporation Rate & Reference:FASTER/N-BUTYL ACETATE
Appearance and Odor:CLEAR, COLORLESS LIQUID WITH LOW ODOR.
Percent Volatiles by Volume:NEGLIG

Stability Indicator/Materials to Avoid:YES
METALLIC CONTAM, AMINES, ORGANIC METAL SALTS & STRONG OXIDIZING &
REDUCING AGENTS, MINERAL ACIDS, ALKALIES, (SUPDAT)
Stability Condition to Avoid:DIRECT SUNLIGHT, HEAT ABOVE 100F, OPEN
FLAME OR SPARKS, CONTAMINATION, PROLONGED STORAGE ABOVE 90F.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE AND
DENSE SMOKE AND INTENSE HEAT.

Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS . THIS
MATL CNTNS METHYL ETHYL KETONE PEROXIDE WHICH IS LISTED AS HAZ
WASTE (NO U160) UNDER SECTION 261.33(F) OF US EPA RCRA REGS. DISP
OF THIS MATL/ITS CNTNRS REQS COMPLIANCE W/APPLIC LABELING, (ING
12)

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.